Potassium bis(sulfamato) bromocuprate

Formula: K2[Cu(SO3NH2)2Br2]

Potassium bis(sulfamato) bromocuprate

Bromine analog of Potassium bis(sulfamato) chlorocuprate

Properties

  • Crystal shape: thick rectangular tablets
  • Color: very dark green, almost indistinguishable from black
  • Stability on air: stable

Preparation

Prepare solution, containing potassium bromide KBr and copper sulfamate Cu(SO3NH2)2 in 2:1 molar ratio and crystallize it.

2KBr + Cu(NH2SO3)2 = K2[Cu(NH2SO3)2Br2].

Growing

Not the easiest material for growing. Has higher solubility compared to the chloride analog, and is more prone to forming parasite crystals. Moreover, solution has very dark color, making it impossible to control growth visually without extracting the crystal.

Safety

The main source of danger is copper: all copper compounds are moderately toxic.

More photos

Potassium bis(sulfamato) bromocuprate

Potassium bis(sulfamato) bromocuprate

When powdered, green coloration is observable:

Potassium bis(sulfamato) bromocuprate

References